Rotational branching ratios and photoelectron angular distributions in resonance enhanced multiphoton ionization of diatomic molecules
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چکیده
Articles you may be interested in Molecular‐orbital decomposition of the ionization continuum for a diatomic molecule by angle‐ and energy‐ resolved photoelectron spectroscopy. I. Formalism Complex angular momentum theory of molecular collisions: New phase rules for rotationally inelastic diffraction scattering in atom–homonuclear diatomic molecule collisions
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Rotational branching ratios and photoelectron angular distributions in resonance enhanced multiphoton ionization of HBr via the F 1Δ2 Rydberg state
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We report calculated ionic rotational branching ratios and associated photoelectron angular distributions for ( 1 + 1') resonance enhanced multiphoton ionization ( REMPI) via the R 21 (20.5), P21 + Q11 (25.5), and P 11 (22.5) branches of theA 2 :I+(3so-) state of NO. The branching ratios are dominated by even angular momentum transfer peaks, in agreement with the ll.N +I= odd (ll.N=.N +N;) sele...
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Rotationally resolved photoelectron spectra in resonance enhanced multiphoton ionization of H2O via the C 1 B 1 Rydberg state Photoelectron studies of resonantly enhanced multiphoton ionization of H2 via the B' 1Σ+ u and D 1Π u states J. Cooper minima are predicted to occur in the 3pu-+ku(/ = 2) and 3pu-+k1T(/ = 2) channels in the resonance enhanced multi photon ionization of NO via the D 2~ + ...
متن کاملRotational branching ratios at low photoelectron energies in resonant enhanced multiphoton ionization of NO
We report calculated rotational branching ratios for very low energy ( 50 me V) photoelectrons resulting from (1 + 1 ') resonant enhanced multiphoton ionization ( REMPI) via the l; = 1/2, 3/2, 5/2, and 7/2levels ofthe P 11 branch of the A l:. + (3sa) state of NO. Even angular momentum transfer (AN=.N +N;) peaks are dominant in these rotational distributions, in agreement with the selection rule...
متن کاملZero kinetic energy-pulsed field ionization and resonance enhanced multiphoton ionization photoelectron spectroscopy: Ionization dynamics of Rydberg states in HBr
The results of rotationally resolved resonance enhanced multiphoton ionization photoelectron spectroscopy and zero kinetic energy-pulsed field ionization studies on HBr via various rotational levels of the F D2 and f D2 Rydberg states are reported. These studies lead to an accurate determination of the lowest ionization threshold as 94 098.961 cm. Observed rotational and spin–orbit branching ra...
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